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响应面法优化煤油水重整制氢工艺条件

Optimization for hydrogen generation process condition of kerosene water reforming by response surface method

  • 摘要: 在单因素实验的基础上,采用响应面法中的Box-Behnken设计对煤油水重整制氢反应的影响因素进行优化,建立煤油水重整制氢反应的二次多项回归模型,并对该模型进行方差分析和可信度分析。实验结果表明:当煤油液空速为0.066 h-1、水碳比为20.2、反应温度为681 ℃时,氢产率最高。预测最大值为33.613 mol氢/mol煤油,与实测值34.028 mol氢/mol煤油基本相符,建立模型有效可靠。

     

    Abstract: On the basis of single factor experiment, the influence factors of hydrogen generation of kerosene water reforming were optimized by Box-Behnken mode of response surface method, a quadratic polynomial regression model of reaction was established, and the variance and reliability of the model were analyzed. The results showed that when the kerosene liquid space velocity was 0.066 h-1, water carbon ratio was 20.2 and the reaction temperature was 681℃, the hydrogen yield achieved the highest level. The predicted maximum hydrogen yield was 33.613 mol/mol, which was almost in consistent with the actual hydrogen yield of 34.028 mol/mol. Therefore, the model was valid and reliable.

     

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