Abstract:
SAPO-34 was undergone by hydrothermal treating with 800 ℃, 100 w% steam for 0-100 h. XRD results showed that the relative crystallinity was decreased with the increase of the hydrothermal treating time. The BET surface area was decreased by 59.6 m
2/g and micropore surface area decreased by 95.0 m
2/g with treating time increased from 0 h to 100 h. NH
3-TPD indicated that when hydrothermal treating time was between 0~45 h, the total acidities sharply deceased, especially the strong acidities. After 45 h, the change of acidities was little. Fixed bed reaction tests showed that when hydrothermal treating time was between 0~45 h, the catalytic life of SAPO-34 was prolonged over two times, while the selectivity for C
2= + C
3= remained nearly the same with SAPO-34 untreated. After 45 h, the selectivity for C
2= + C
3= was improved greatly but catalyst life didn't chang. The yield of C
2= + C
3= was up to 7.43%.