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川东地区超深超高温储层高温胶凝酸酸岩反应动力学室内研究与实践

An experimental study on kinetics of acid-rock reaction for carbonate reservoir in Sinian system of east Sichuan Basin

  • 摘要: 酸岩反应动力学参数是分析酸岩反应特征、评价酸液体系及酸压设计的关键基础参数,为正确分析酸岩反应速率规律、指导酸压施工设计提供基础。通过开展用于四川盆地川东下古生界-震旦系的180 ℃高温胶凝酸酸岩反应动力学实验,建立了酸岩反应动力学方程,得到了180 ℃、500 r/min、7 MPa条件下,酸岩反应级数m=0.696 9,反应速度常数K=1.09×10-4(mol·L)-m·mol/(cm2·s),反应速度方程为J=1.09×10-4C0.696 9;其活化能Ea=23 706 J/mol,酸岩反应动力学方程为J=0.070 5e-23 706/RTC0.696 9;并明确了胶凝酸的温度、酸液浓度对反应速度的影响程度。

     

    Abstract: Kinetics parameters of acid-rock reaction are basic parameters to analyze the character of acid-rock reaction, and evaluate the acid liquid system and acid pressure design, which provide the basis of analyzing reaction rate correctly and guiding acidizing/acid fracturing design. By conducting the kinetics experiments of jel acid/rock reaction at 180 ℃ in Sinian system of east Sichuan basin, the acid-rock reaction kinetics equation can be established. The results show that under the conditions of 180 ℃, 500 r/min, 7 MPa, acid/rock reaction order m=0.696 9, reaction rate constant K=1.09×10-4(mol·L)-m·mol/(cm2·s), reaction rate equation is J=1.09×10-4C0.696 9, its activation energy Ea=23 706 J·mol-1, the acid rock kinetic equation is J=0.070 5e-23 706/RTC0.696 9. The effects of the temperature and concentration of jel acid on the reaction speed are determined.

     

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