Abstract:
Kinetics parameters of acid-rock reaction are basic parameters to analyze the character of acid-rock reaction, and evaluate the acid liquid system and acid pressure design, which provide the basis of analyzing reaction rate correctly and guiding acidizing/acid fracturing design. By conducting the kinetics experiments of jel acid/rock reaction at 180 ℃ in Sinian system of east Sichuan basin, the acid-rock reaction kinetics equation can be established. The results show that under the conditions of 180 ℃, 500 r/min, 7 MPa, acid/rock reaction order
m=0.696 9, reaction rate constant
K=1.09×10
-4(mol·L)
-m·mol/(cm
2·s), reaction rate equation is
J=1.09×10
-4C
0.696 9, its activation energy
Ea=23 706 J·mol
-1, the acid rock kinetic equation is
J=0.070 5e
-23 706/RTC
0.696 9. The effects of the temperature and concentration of jel acid on the reaction speed are determined.