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油基钻井液高效除硫体系优化实验

Optimization experiment of efficient hydrogen sulfide removal system for oil-based drilling fluid

  • 摘要:
    目的 解决川东北含硫气藏在钻井过程中存在的H2S污染油基钻井液、H2S溢出造成的安全风险问题。
    方法 建立了H2S污染油基钻井液室内评价方法和评价参数,优选了油基钻井液用高效除硫剂和复合除硫体系配方。
    结果 除硫效果优异的单剂为液体除硫剂YT-1、碱式碳酸锌JD-2、醇醚酰胺CLC,饱和度分别为56.48 mg/g、21.13 mg/g、5.8 mg/g,高温老化除硫率分别为90.10%、82.60%和75.23%,与油基钻井液配伍性良好。优化形成的复合除硫体系配方4%(w)YT-1+2%(w)JD-2,在质量浓度为75 mg/L的H2S污染油基钻井液后,出口质量浓度达到0.015 mg/L所用时间仅为1.21 min,加入复合除硫体系后,该时间则达到171.8 min。污染后的油基钻井液高温老化后H2S质量浓度为0.078 mg/L,加入复合除硫体系后,H2S质量浓度为0 mg/L,除硫率达100%。
    结论 除硫单剂协同作用提高除硫效果,为川东北地区高含硫地层“安全、高效”钻井提供了技术保障。

     

    Abstract:
    Objective The sulfur remover suitable for oil-based drilling fluid was studied to solve the problems, such as pollution of oil-based drilling fluid by hydrogen sulfide and safety risk caused by hydrogen sulfide overflow in the drilling process of sulfur-bearing gas reservoir in northeastern Sichuan.
    Methods The evaluation method and parameters of oil-based drilling fluid contaminated by hydrogen sulfide were established. The formulation of high efficiency sulfur removal agent and compound sulfur removal system for oil-based drilling fluid were optimized.
    Results The single agents with excellent sulfur removal effect were liquid sulfur removal agent YT-1, zinc carbonate basic JD-2 and alcohol ether amide CLC, with the saturation of 56.48 mg/g, 21.13 mg/g and 5.8 mg/g, respectively, the high temperature aging sulfur removal rates of 90.10%, 82.60% and 75.23%, and they showed good compatibility with oil-based drilling fluid. The compound sulfur removal system formulation of 4%YT-1+2%JD-2 was optimized. For the 75 mg/L hydrogen sulfide contaminated oil-base drilling fluid, the time to reach the outlet concentration of 0.015 mg/L was only 1.21 min, which reached 171.8 min after adding the compound sulfur removal system. The H2S concentration of the contaminated oil-based drilling fluid was 0.078 mg/L after high temperature aging, and the H2S concentration was 0 mg/L after adding the compound sulfur removal system, and the sulfur removal rate reached 100%.
    Conclusions The single agent of sulfur removal can improve the sulfur removal effect, providing technical support for the safe and efficient drilling in the high sulfur formation in northeastern Sichuan.

     

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