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天然气脱水装置三甘醇携带损失影响因素及控制措施

Influencing factors and control measures of triethylene glycol carrying loss of natural gas dehydration unit

  • 摘要:
    目的 通过分析影响三甘醇携带损失的主要因素,提出降低三甘醇携带损失量的措施。
    方法 以某天然气脱水站运行中的三甘醇溶液为研究对象,通过实验分别分析了三甘醇中含铁化合物质量浓度、三甘醇中缓蚀剂与消泡剂质量浓度、三甘醇中甲基二乙醇胺(MDEA)与硫化氢(H2S)质量浓度、三甘醇中烃类质量浓度、天然气进吸收塔温度、天然气进吸收塔压力、天然气处理量和重沸器温度对三甘醇携带损失量的影响,并采用灰色关联度方法确定了其中的主控因素。
    结果 三甘醇中含铁化合物质量浓度、三甘醇中缓蚀剂和烃类质量浓度等因素是影响三甘醇携带损失量的主控因素,引起三甘醇携带损失的主要原因是三甘醇发泡使气体携带的三甘醇液滴增加。
    结论 从天然气带入三甘醇中的杂质是引起三甘醇携带损失量增大的主要原因,而工艺参数的变化对其影响不大。通过采取控制进入吸收塔天然气的气质、在高压低温的条件下运行及在吸收塔出口天然气管线上增设分离器等措施,可减少三甘醇的携带损失量。

     

    Abstract:
    Objective The aim is to put forward measures to reduce the carrying loss of triethylene glycol (TEG) by analyzing the main factors affecting the carrying loss of triethylene glycol.
    Method Taking the TEG solution in the operation of a natural gas dehydration station as the research object, the influences of various factors on TEG carrying loss were analyzed. These factors included iron-containing compounds mass concentration in TEG, corrosion inhibitors and defoamers mass concentration in TEG, methyldiethanolamine (MDEA) and hydrogen sulfide (H2S) mass concentration in TEG, hydrocarbons mass concentration in TEG, the temperature of natural gas into the absorber, the pressure of natural gas into absorber, the natural gas processing capacity and the reboiler temperature. The grey correlation method was used to identify the main controlling factors.
    Result The factors such as mass concentration of iron-containing compounds, corrosion inhibitors and hydrocarbons in TEG were the main controlling factors affecting the triethylene glycol carrying loss. The primary cause of the carrying loss of triethylene glycol was identified as the triethylene glycol foaming, which increased the triethylene glycol droplets carried by the gas.
    Conclusion The impurities brought from the natural gas into the triethylene glycol are the main reason for the increase in carrying loss of triethylene glycol, and the change of process parameters has little effect. The carrying loss of triethylene glycol can be reduced by controlling the impurity content in the natural gas entering the absorber, operating at high pressure and low temperature, and installing a separator on the natural gas pipeline at the outlet of the absorber.

     

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