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天然气净化厂砜胺溶液体系发泡特性研究

Research on foaming characteristics of sulfone amine solution system in natural gas purification plant

  • 摘要:
    目的 研究砜胺脱硫溶液体系的发泡特性和发泡因子(K)的取值。
    方法 ①根据SY/T 6538—2016《配方型选择性脱硫溶剂》对砜胺溶剂进行发泡实验,对起泡高度和消泡时间等关键参数进行分析,采用相对泡沫密度(Φ)对砜胺溶液体系的发泡特性进行半定量描述,考查液层高度、气速和温度等对发泡的影响;②采用将砜胺溶液体系的发泡情况与已知发泡因子的溶液体系进行对比的方法推测K值。
    结果 ①增加液层高度对砜胺贫液发泡比的影响较大,初始液层高度从30 mm增至100 mm 时,其发泡比从360%降至251%,但半衰期均在完全消泡时间的约50%处达到;②起泡高度随气速的增大而降低,气速越大,消泡速率越慢,泡沫稳定性越好;③消泡速率随温度的升高而加快;④新鲜砜胺溶液和MDEA水溶液的发泡因子接近,但实验装置的砜胺溶液K值推测为0.55~0.64,发泡趋势明显升高。
    结论 该实验结果可为基于砜胺溶液体系的天然气净化厂的设计提供参考。

     

    Abstract:
    Objective The aim is to study the foaming characteristics and the value of the foaming factor (K) of the sulfone amine desulfurization solution system.
    Method Firstly, in accordance with SY/T 6538—2016 Formulated selective desulfurization solvent, foaming experiments of sulfone amine solvents were conducted. The Key parameters such as foaming height and defoaming time were analyzed. The foaming characteristics of the sulfone amine solution system were semi-quantitatively described using relative foam density (Φ). The effects of liquid layer height, gas velocity, and temperature on foaming were investigated. Secondly, the K value was inferred by comparing the foaming condition of the sulfone amine solution system with the solution systems of known foaming factors.
    Result Firstly, increasing the liquid layer height significantly affected the foaming ratio of the sulfone amine lean solution. When the initial liquid layer height was increased from 30 mm to 100 mm, the foaming ratio decreased from 360% to 251%, but the half-life reached approximately 50% of the complete defoaming time. Secondly, the foaming height decreased with the increase of the gas velocity. The higher the gas velocity, the slower the defoaming rate and the better the foam stability. Thirdly, the defoaming rate increased with the rising of the temperature. Fourthly, the K value of fresh sulfone amine solution was close to that of MDEA aqueous solution, but the K value of the sulfone amine solution in the experimental device was speculated to be 0.55-0.64, and the foaming trend was obviously improved.
    Conclusion These experimental results can provide a reference for the design of natural gas purification plants based on sulfone amine solution system.

     

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