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纳米复合减阻剂的制备及应用性能评价

Preparation and application performance evaluation of nano-composite drag reducer

  • 摘要:
    目的 针对在高温高盐储层中聚丙烯酰胺减阻剂性能不稳定、耐温耐盐性差的问题,开发出一种纳米复合减阻剂,并通过添加助剂形成具有良好耐温耐盐性能的滑溜水压裂液体系。
    方法 以AM、AMPS、疏水单体DMHAAB和KH-570改性的纳米SiO2为原料,制备了纳米复合减阻剂ZJYD-SiO2,通过减阻率测试结果优选出最优含量后,通过破胶液的黏度、界面活性等参数优选了破胶剂过硫酸铵、助排剂十八烷基羟基磺基甜菜碱,构筑出了纳米复合滑溜水压裂液ZJYD-SiO2体系。通过ZJYD-SiO2体系与不加改性纳米SiO2的减阻剂ZJYD构成的滑溜水压裂液体系进行了一系列性能指标对比,包括不同实验条件下的减阻性能、流变性能对比等。
    结果 在减阻性能方面,ZJYD-SiO2体系的减阻率随流量增大先增大后减小,随温度、矿化度、管径的变大而减小,但减阻率大于ZJYD体系,且始终大于70%。在黏弹性测试方面,前者储能/损耗模量均大于后者,耐温耐剪切测试方面,前者黏度衰减低于后者;支撑剂的沉降速率测试方面也表现出同样结果。
    结论 ZJYD-SiO2体系的各项关键性能均优于ZJYD体系,说明纳米复合减阻剂具有良好的应用性能。纳米材料的引入使得聚合物链的伸展能力加强,形成了更为稳定的空间网络结构。

     

    Abstract:
    Objective To address the instabile properties and poor thermal/salt tolerance of polyacrylamide drag reducers in high-temperature/high-salinity reservoirs, this study developed a nano-composite drag reducer integrated with additives to establish an advanced slick water fracturing fluid system with a significant thermal/salt tolerance.
    Method The nano-composite drag reducer ZJYD-SiO2 was prepared using AM, AMPS, hydrophobic monomer DMHAAB and KH-570 modified nano-SiO2 as raw materials. After the optimal concentration was selected based on the drag reduction rate test results, the breaker ammonium persulfate and the clean up additive cocoyl hydroxyethyl betaine were selected based on parameters such as the viscosity of the breaker fluid and interfacial activity, and the nano-composite slick water fracturing fluid ZJYD-SiO2 system was constructed. A series of performance index comparisons were made between the slick water fracturing fluid system composed of ZJYD-SiO2 and the drag reducer ZJYD without modified nano-SiO2, including drag reduction performance and rheological performance under different experimental conditions.
    Result The results showed that in terms of drag reduction performance, the drag reduction rate of the slick water fracturing fluid system first increased and then decreased with the increase of flow rate, and decreased with the increase of temperature, salinity and pipe diameter. However, the drag reduction rate was always greater than 70% and higher than that of the ZJYD system. In terms of viscoelasticity tests, the energy storage/loss modulus was greater than that of the latter. In terms of temperature and shear resistance tests, the viscosity attenuation of the former was lower than that of the latter. The settling rate test of proppants also showed the same trend.
    Conclusion The key properties of the ZJYD-SiO2 system are superior to those of the ZJYD system, indicating that the nano-composite drag-reducer has excellent application performance. The introduction of nano-materials can enhance the extensibility of the polymer chain, forming a more stable spatial network structure.

     

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