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三嗪注入法天然气脱硫工艺研究进展

Research progress of natural gas desulfurization process by triazine injection method

  • 摘要: 天然气作为低碳转型的关键能源,其高效脱硫技术是实现天然气清洁利用的核心环节。介绍了三嗪注入法在天然气脱硫领域的技术进展与挑战,重点分析了其反应机理、工艺创新及废液处理策略。三嗪类脱硫剂通过亲核取代反应脱除硫化物,其反应速率受到反应溶液pH、反应温度及取代基团的影响,对海上平台和边远气田具有显著的优势。三嗪注入法的工业应用结果表明,可将单井天然气处理成本降至0.04~0.10元/m3。然而,该技术仍存在废液处理能耗高及资源化路径有限等瓶颈问题。在当前的废液处理技术中,酸析−氧化联用与纳滤膜分离可将COD降至120~230 mg/L,石墨烯泡沫吸附可实现99%的COD去除率。针对未来的发展,提出以下建议:①构建生物基三嗪衍生物体系,以降低环境足迹;②开发硫醇定向清除功能材料,以提升有机硫的脱除能力;③创新将DTZ废渣改性为橡胶填料的资源化路径。通过上述工艺的耦合,可推动三嗪技术向低碳化、智能化方向发展,为高含硫气田的开发及碳达峰碳中和目标的实现提供重要的技术参考。

     

    Abstract: Natural gas is the key energy for low-carbon transformation, and its efficient desulfurization technology is the core link to realize the clean utilization of natural gas. The technical progress and challenges of the triazine injection method in the field of natural gas desulfurization were introduced. The reaction mechanism, process innovation and waste liquid treatment strategy were emphatically analyzed. Triazine-based desulfurizing agents remove sulfides through nucleophilic substitution reactions, with reaction rates affected by the pH of the reaction solution, the reaction temperature, and the substituent group, which has significant advantages for offshore platforms and remote gas fields. The industrial application results of the triazine injection method showed that the cost of single well natural gas treatment can be reduced to 0.04-0.10 CNY/m3. However, the technology still has bottleneck problems, such as high energy consumption of waste liquid treatment and a limited recycling path. In the current wastewater treatment technology, the acid precipitation-oxidation coupling and nanofiltration membrane separation can reduce COD to 120-230 mg/L, while graphene foam adsorption can achieve 99% COD removal rate. In view of the future development, the following suggestions are put forward: Firstly, constructing a bio-based triazine derivative system to reduce the environmental footprint. Secondly, developing thiol directional removal functional materials to enhance the removal ability of organic sulfur. Thirdly, innovating the resource path to modify DTZ waste residue into rubber filler. Through the coupling of the above processes, the triazine technology can be promoted to develop in the direction of low carbonization and intelligence, which can provide an important technical reference for the development of high-sulfur gas fields and the realization of the carbon peaking and carbon neutrality goals.

     

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