高级检索

可再生天然气脱汞剂吸附脱附特征研究

Study on adsorption and desorption characteristics of renewable natural gas mercury removal agent

  • 摘要:
    目的 研究可再生脱汞剂的低温吸附和高温脱附特征,以期对工艺参数的选择提供参考。
    方法 开展了不同温度下的可再生脱汞剂吸附实验及不同程序升温条件下的脱附实验研究。
    结果 可再生脱汞剂在20~80 ℃的范围内对汞蒸气均具有吸附作用,但温度越高,吸附能力越弱。恒速升温脱附实验结果显示,脱汞剂的脱附曲线呈现出双峰特征,主峰峰面积占据主导地位。恒温温度越高,可再生脱汞剂的汞脱附率越高,恒温时间和吸附时间对可再生脱汞剂的汞脱附率影响较小。
    结论 可再生天然气脱汞吸附温度宜控制在60 ℃以下;考虑到钢材的耐温性和再生能耗,再生时的恒温温度宜控制在300 ℃左右。

     

    Abstract:
    Objective The aim is to study the characteristics of low-temperature adsorption and high-temperature desorption of a renewable mercury removal agent, in order to provide references for the selection of process parameters.
    Method The adsorption experiments of renewable mercury removal agents at different temperatures and the desorption experiments under different programmed heating conditions were carried out.
    Result The renewable mercury removal agent had adsorption capabilities for mercury vapor at 20-80 ℃, but the higher the temperature, the weaker its adsorption capacity. The results of the constant rate heating desorption experiment showed that the desorption curve of the mercury removal agent exhibited a bimodal characteristic, with the main peak area dominating. The higher the constant temperature, the higher the mercury desorption rate of the renewable mercury removal agent. The constant temperature time and adsorption time had little effect on the mercury desorption rate of the renewable mercury removal agent.
    Conclusion The adsorption temperature of the renewable natural gas mercury removal should be controlled below 60 ℃. Considering the temperature resistance of steel and regeneration energy consumption, the constant temperature during regeneration should be controlled at about 300 ℃.

     

/

返回文章
返回