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延安气田安塞区域井筒堵塞物分析及自生酸解堵体系研究

Analysis of wellbore blockage in the Ansai area of Yan'an Gasfield and study on the self-generated acid blocking removal system

  • 摘要:
    目的 延安气田安塞区域属于低压、低渗、低丰度的“三低气藏”,非均质性强。该气田水矿化度高,Ca2+、Mg2+、Ba2+、Sr2+等高价离子含量很高,开采过程中随着温度、压力的变化,井筒极易结垢,形成垢堵。对于此类矿化度较高的“三低气藏”,需要有针对性地解堵,从而提高产能。
    方法 采用电感耦合等离子体发射光谱(inductively coupled plasma, ICP)、X射线衍射(X-ray diffraction, XRD)、离子色谱(ion chromatography, IC)等分析手段对气田水样、垢样进行了分析,研究了气田结垢趋势,开发了螯合型自生酸解堵体系,并对解堵体系进行了性能评价。
    结果  研究表明,该区域气井的堵塞物主要是地层水结垢、黏土矿物运移以及腐蚀产物沉积等垢堵物,确定了该地区井筒垢堵主要类型为碳酸盐垢。形成了CN螯合型自生酸解堵体系,垢溶蚀率达到80.8%,垢堵岩心的伤害恢复率为73.62%,现场应用后日产气量从0.2×104 m3提升至1.5×104 m3以上。
    结论 针对该区域气田研发的自生酸解堵工作液不仅可以溶蚀井筒堵垢,还可螯合成垢离子,使其不易成垢,在现场应用中取得了良好的解堵效果。

     

    Abstract:
    Objective  The Ansai area of the Yan'an Gasfield is a "three-low gas reservoir" with low pressure, low permeability and low abundance, and has strong heterogeneity. The gas field water has high salinity, and the content of high valence ions such as Ca2+, Mg2+, Ba2+ and Sr2+ is very high. With the change of temperature and pressure in mining, the wellbore is easy to scaling and form scale plugging. For such “three low gas reservoir” with highly mineralized, targeted blocking removal is needed to improve productivity.
    Method Inductively coupled plasma (ICP), X-ray diffraction (XRD), ion chromatography (IC) and other analytical methods were used to analyze the water samples and scale samples of the gas field, and the scaling trend of the gas field was studied. The chelating self-generated acid blocking removal system was developed, and the performance of the blocking removal system was evaluated.
    Result The research showed that the blockages of gas wells in this area were mainly blockages such as formation water scaling, clay mineral migration and corrosion product deposition. It was determined that the main type of wellbore scale blockage in this area was carbonate scale. A CN chelating self-generated acid blcoking removal system was formed, the scale dissolution rate was 80.8%, the damage recovery rate of the scale blocking core was 73.62%, and the daily gas production increased from 2 000 m3 to more than 15 000 m3 in field application.
    Conclusion  The self-generated acid blocking removal working fluid developed for the gas field in this area can not only dissolve the wellbore blocking, but also chelate the scale ions, so that it is not easy to scale, and has achieved a good effect of blocking removal in field application.

     

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