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新疆油田CCUS示范区采出井缓蚀剂优选评价及应用

Evaluation and application of corrosion inhibitors for production wells in the CCUS demonstration area of Xinjiang Oilfield

  • 摘要:
    目的 解决新疆油田碳捕集、利用与封存(carbon capture, utilization and storage, CCUS)采出井高CO2和高Cl含量环境下井筒高效低成本腐蚀防护问题。
    方法 通过电化学测试在常压、60 ℃、苛刻矿化度环境中筛选出最适宜的缓蚀剂,并测试了不同区块井筒温度条件下的缓蚀率,通过分子动力学模拟揭示了温度对优选缓蚀剂在钢材表面吸附的影响机制,通过高温高压釜实验得到了模拟工况下缓蚀剂的防护效果,通过长周期井下挂环明确了现场应用效果。
    结果 室内实验结果表明,在高含CO2环境下,喹啉季铵盐缓蚀效果较优,缓蚀率大于90%,当温度从50 ℃升高至80 ℃时,其缓蚀率从94.86%降至90.86%,温度升高导致缓蚀剂分子吸附能降低,防护性能减弱。现场应用结果表明,新疆油田CCUS示范区主力区块缓蚀剂加注质量浓度降低至200 mg/L后,井筒腐蚀速率可控制在0.059 2 mm/a以内。
    结论 喹啉季铵盐缓蚀剂在高CO2和高Cl含量环境下缓蚀性能优异,可用于CO2驱采出工况井筒的腐蚀控制。

     

    Abstract:
    Objective In order to solve the problem of efficient and low-cost corrosion protection of the wellbore in carbon capture, utilization and storage (CCUS) production wells in Xinjiang Oilfield in an environment with high CO2 and high Cl content.
    Method  The most suitable corrosion inhibitor was selected through electrochemical testing in an environment of atmospheric pressure, 60 ℃, and harsh salinity, and the corrosion inhibition rates under wellbore temperature conditions in different blocks were tested. Molecular dynamics simulation revealed the influence mechanism of temperature on the adsorption of the selected corrosion inhibitor on the surface of steel. The protective effect of the corrosion inhibitor under simulated working conditions was obtained through high-temperature and high-pressure autoclave experiments, and the field application effect was clarified through long-period underground hanging rings.
    Result Laboratory experimental results showed that quinoline quaternary ammonium salt had a better corrosion inhibition in high CO2-containing environments, with a corrosion inhibition rate of more than 90%. When the temperature increased from 50 ℃ to 80 ℃, its corrosion inhibition rate decreased from 94.86% to 90.86%. The increase of temperature reduced the molecular adsorption energy of the corrosion inhibitor and weakened the protective performance. Field application results showed that after the corrosion inhibitor injection concentration in the main block of the CCUS demonstration area of Xinjiang Oilfield was reduced to 200 mg/L, the wellbore corrosion rate could be controlled within 0.0592 mm/a.
    Conclusion Quinoline quaternary ammonium salt corrosion inhibitor has excellent corrosion inhibition performance in a high CO2 and high Cl content environment and can be used for corrosion control in wellbores under CO2 flooding production conditions.

     

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