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一种具有稠油降黏作用的新型携砂液研究与应用

Research and application of a new type of sand-carrying fluid with a viscosity-reducing effect on heavy oil

  • 摘要:
    目的 在桩斜139块稠油油藏实施高压充填防砂或压裂防砂改善油流通道,由于原油黏度高,现场采用挤降黏剂方式降低原油黏度,改善原油流动性,但工艺繁琐,作业费用高。为降低措施成本,开展了具有稠油降黏作用的新型携砂液研究与应用。
    方法 以丙烯酰胺、丙烯酸、Gemini型阳离子表面活性剂和2-丙烯酰胺基烷基磺酸为单体,通过水溶液聚合制备了一种疏水缔合聚合物。采用红外光谱进行了结构表征,并与黏弹性表面活性剂、pH调节剂复配,制备了一种具有稠油降黏作用的携砂液。室内评价了其黏度、剪切、携砂、破胶、降黏等性能。
    结果 红外光谱验证了聚合物具有疏水单体结构单元,研制的携砂液初始黏度为240 mPa·s;在温度为90 ℃、剪切速率为170 s−1下,剪切120 min后的黏度为75 mPa·s;在90 ℃下恒温处理60 min后,粒径为0.425~0.850 mm的石英砂沉降速率为0.77 mm/s,携砂性能好。加入过硫酸铵在90 ℃下破胶完全后,破胶液黏度2.37 mPa·s,表面张力26.34 mN/m,界面张力1.36 mN/m,对桩西稠油井降黏率达98%以上。现场应用12井次,平均单井用量179 m3,单井加砂23.2 m3。措施开井后平均单井日增油4.3 t。
    结论 在稠油油藏,采用该携砂液实施高压充填防砂后,无需再进行降黏施工,即可显著提升稠油产量,为稠油油藏的防砂治理提供了高效的技术解决方案。

     

    Abstract:
    Objective  The purpose of implementing high-pressure filling sand control or fracturing sand control in the 139 block heavy oil reservoir is to improve the oil flow channel. Due to the high viscosity of the heavy oil, a viscosity-reducing agent is used to reduce its viscosity and improve its fluidity. However, the process is complex and costly. To reduce the application cost, a new type of sand-carrying fluid with a viscosity-reducing effect on heavy oil was developed.
    Method A hydrophobic associative polymer was developed by aqueous solution polymerization using acrylamide, acrylic acid, Gemini cationic surfactant, and 2-acrylamidoalkyl sulfonic acid as monomers. The polymer structure was characterized by infrared spectroscopy. Combined with viscoelastic surfactant and pH regulator, a sand-carrying fluid with heavy oil viscosity-reducing effect was developed. Its viscosity, shear resistance, sand-carrying capacity, gel breaking performance, and viscosity reduction efficiency were evaluated in the laboratory.
    Results The existence of hydrophobic monomer structural units in the polymer was verified by infrared spectroscopy. The initial viscosity of the sand-carrying fluid was 240 mPa·s. At the temperature of 90 ℃ and the shear rate of 170 s−1, the viscosity of the sand-carrying fluid after shearing for 120 minutes was 75 mPa·s. After the sand-carrying fluid was maintained at a constant temperature of 90 ℃ for 60 minutes, the settling rate of 0.425~0.850 mm quartz sand was 0.77 mm/s, indicating that the sand-carrying fluid has good sand-carrying performance. After adding ammonium persulfate and completely breaking the gel at 90 ℃, the viscosity of the gel-breaking fluid was 2.37 mPa·s, the surface tension was 26.34 mN/m, and the interfacial tension was 1.36 mN/m, achieving a viscosity reduction rate of over 98% for the heavy oil in Zhuangxi. The sand-carrying fluid was used in 12 wells in this reservoir. The average consumption of the sand-carrying fluid for a single well was 179 m3, and a sand addition was 23.2 m3 for a single well. Due to the effects of the sand-carrying fluid, the average oil production rate per well increased by 4.3 t/d.
    Conclusion In heavy oil reservoirs, the use of this sand-carrying fluid for high-pressure sand control can significantly increase heavy oil production without the need for viscosity reduction construction. This study provides an efficient technical solution for sand control in heavy oil reservoirs.

     

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