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高效节能碳捕集溶剂与工艺研究

Study on high-efficiency and energy-saving carbon capture solvent and process

  • 摘要:
    目的 针对胺法碳捕集技术存在的再生能耗高与溶剂降解问题,研究高效节能的吸收溶剂及其配套工艺,以降低运行成本。
    方法 ①通过分析不同溶剂的反应机理与能耗特性,研发了多元复合溶剂CT8-23B;②引入pH调控辅助再生工艺,利用弱酸盐构建缓冲体系以加速解吸;③评估了级间冷却、机械蒸汽再压缩等工艺的节能效果。
    结果 与质量分数为30%的MEA相比,CT8-23B溶剂的CO2吸收速率相当,饱和吸收容量提高27%,解吸速率提升100%,再生能耗降低约30%;pH调控辅助再生工艺可进一步强化再生过程,降低能耗。
    结论 CT8-23B溶剂与pH调控辅助再生等节能工艺相结合,可显著降低碳捕集工艺的能耗,且具备良好的工业应用与改造潜力,提供了一种低成本的碳捕集技术方案。

     

    Abstract:
    Objective To address the issues of high regeneration energy consumption and solvent degradation in amine carbon capture technology, an efficient and energy-saving absorption solvent and its corresponding process were studied to reduce operating costs.
    Method First, by analyzing the reaction mechanisms and energy consumption characteristics of different solvents, a multi-component composite solvent, CT8-23B, was developed. Second, a pH-regulation-assisted regeneration process was introduced, in which a weak-acid salt was used to establish a buffer system to accelerate desorption. Third, the energy-saving performance of interstage cooling, mechanical vapor recompression, and other processes was evaluated.
    Result Compared with 30 wt% MEA, the CT8-23B solvent exhibited a comparable CO2 absorption rate. In addition, the saturated absorption capacity was increased by 27%, the desorption rate was increased by 100%, and the regeneration energy consumption was reduced by about 30%. Furthermore, the pH-regulation-assisted regeneration process can further enhance the regeneration performance and reduce energy consumption.
    Conclusion The combination of the CT8-23B solvent with energy-saving processes such as the pH-regulation-assisted regeneration process can significantly reduce the energy consumption of the carbon capture process, and has good industrial application and retrofit potential, providing a low-cost carbon capture technology solution.

     

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