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缔合型超分子聚合物泡沫修井液的研制及性能评价

Development and performance evaluation of supramolecular associative polymer foam workover fluid

  • 摘要:
    目的 针对国内页岩气生产井修井作业中常规修井液经常发生漏失、井口失返与修井后产能下降等问题,研制出一种以缔合型超分子聚合物4DH为稳泡剂、聚醚磺酸盐类复合物FY-2055为起泡剂的缔合型超分子聚合物泡沫修井液。
    方法 筛选优化体系配方,对比了几种常规泡沫体系性能与泡沫显微形态,评价了高温高压泡沫性能,同时对比了该泡沫体系与常规聚合物HPAM体系的泡沫堵漏与渗透率恢复性能。
    结果 体系最优配方(w)为0.15%~0.30% 4DH+0.30% FY-2055,较表面活性剂体系与常规聚合物HPAM体系具有更加优秀的泡沫性能与泡沫结构强度,且泡沫密度具有可调性,在9.5~10.0 MPa与120~150 ℃条件下稳泡时间大于90 min、耐温耐剪切黏度大于50 mPa·s,岩心渗透率恢复率高达100 %,对储层无伤害或伤害性很小,较相同条件下的常规聚合物HPAM泡沫体系(渗透率恢复率约为30%)具有明显优势。
    结论 综合各方面性能,该超分子泡沫修井液可进行现场应用先导试验。

     

    Abstract:
    Objective To address the problems of fluid loss, wellhead return loss, and productivity decline frequently encountered in conventional workover fluids during workover operations in shale gas production wells of China, a supramolecular associative polymer foam workover fluid was developed using the supramolecular associative polymer 4DH as a foam stabilizer and the polyether sulfonate composite FY-2055 as a foaming agent.
    Method  The system formulation was screened and optimized. The properties and microscopic morphology of several conventional foam systems were compared, and the high-temperature and high-pressure foam properties were evaluated. Meanwhile, the foam plugging and permeability recovery performance of this foam system was compared with that of the conventional HPAM system.
    Result The optimal formulation of the system is 0.15%-0.30% 4DH + 0.30% FY-2055. Compared with the surfactant system and the conventional HPAM system, it exhibits superior foam properties and foam structural strength, and the foam density is adjustable. Under the conditions of 9.5−10 MPa and 120−150 ℃, the foam stability time exceeds 90 min, the temperature- and shear-resistant viscosity exceeds 50 mPa·s. Simultaneously, the core permeability recovery rate reaches 100%, indicating no or minimal damage to the reservoir, which demonstrates significant advantages over the conventional HPAM foam system (permeability recovery rate of approximately 30%) under the same conditions.
    Conclusion Based on its comprehensive performance, this supramolecular foam workover fluid can be recommended for field application pilot testing.

     

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