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摘要: |
本实验在钯催化体系的基础上,研究了添加金属化合物对甲酸甲酯异构化反应的影响,发现镍添加物对甲酸甲酯异构化反应有利,而锡金属化合物对催化活性有毒害作用,钯-镍双金属在甲酸异构化反应中表现一定的协同作用,考察了三苯基磷量,反应时间对该反应体系的影响。 |
关键词: 镍化合物 钯 催化剂 甲酸甲酯 异构化 催化 |
DOI: |
分类号:TQ225.41 O643.321 |
基金项目: |
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Pd-Ni Catalyzed the Isomerization of Methyl Formate to Acetic Acid. |
Wang Junwei Yang Xiangui Zhang Jiaqi et al.
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Abstract: |
The isomerization of methyl formate to acetic acid catalyzed by Pd-Ni system has been investigated. Under the optimum conditions, the yield of acetic acid is higher than 94%. The results indicate that the addition of nickel complex improved the activity o |
Key words: palladium-nickel,methyl formate,catalysts,acetic acid |