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Wang Lu, Yang Jingyi, Xu Xinru. Research on Relationships between Structure of Amine and Its Reaction Rate with CO2[J]. Chemical Engineering of Oil & Gas, 2010, 39(2): 95-100. DOI: 10.3969/j.issn.1007-3426.2010.02.002
Citation: Wang Lu, Yang Jingyi, Xu Xinru. Research on Relationships between Structure of Amine and Its Reaction Rate with CO2[J]. Chemical Engineering of Oil & Gas, 2010, 39(2): 95-100. DOI: 10.3969/j.issn.1007-3426.2010.02.002
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Research on Relationships between Structure of Amine and Its Reaction Rate with CO2

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  • The intimate connection between protonation constant (pKa), sterically hindered constant (-Es) of amine and its reaction rate with CO2 was found from the reaction rate data of 30 primary and secondary amines, 5 tertiary amines with CO2. The relationship was proved by BP Neural Net.The net could be a reliable tool for forecasting the reaction rate constant.
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