Experimental study on influence of Ca2+ and Mg2+ on performance of Cr3+ polymer gel
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Graphical Abstract
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Abstract
In order to explore the function mechanism of Ca2+ and Mg2+ on weak polymer gel displacement, aiming at geological characteristics and fluid property of one reservoir in Bohai Oilfield, this paper studied on the influence of Ca2+ and Mg2+ on displacement effect of Cr3+ polymer gel through evaluating increasing viscosity, shear resistance, temperature tolerance, viscoelasticity, seepage characteristic and displacement effect, with taking viscosity, viscoelasticity, resistance factor, residul resistance factor and oil recovery as evaluation factor. The results show that, compared with injection water, although softened water has higher salinity, it almost doesn't contain Ca2+ and Mg2+. Polymer molecular chains of Cr3+ polymer gel prepared by softened water suffer less influence of Ca2+ and Mg2+ divalent catio, and have bigger polymer molecular aggregation size, its increasing viscosity, shear resistance, temperature tolerance, viscoelasticity, seepage characteristic and displacement effect are all stronger than Cr3+ polymer gel prepared by injection water. Using softening process for offshore oilfield injection water, which means eliminating Ca2+ and Mg2+, is good for improving displacement effect of Cr3+ polymer gel, and furtherly enhancing oil recovery.
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