Advanced Search
Gong Xu, Wang Zongxian, Liu He. Polycyclic aromatic hydrocarbons aided with iron salts hydrogenation by using in situ hydrogen generated through the CO water gas shift reaction[J]. Chemical Engineering of Oil & Gas, 2018, 47(1): 74-78. DOI: 10.3969/j.issn.1007-3426.2018.01.014
Citation: Gong Xu, Wang Zongxian, Liu He. Polycyclic aromatic hydrocarbons aided with iron salts hydrogenation by using in situ hydrogen generated through the CO water gas shift reaction[J]. Chemical Engineering of Oil & Gas, 2018, 47(1): 74-78. DOI: 10.3969/j.issn.1007-3426.2018.01.014
shu

Polycyclic aromatic hydrocarbons aided with iron salts hydrogenation by using in situ hydrogen generated through the CO water gas shift reaction

    Graphical Abstract
    • Abstract
  • The effect of anthracene hydrogenation with CO water gas shift as a model for polycyclic aromatic hydrocarbons under different conditions was investigated, and the synergistic effect between anthracene hydrogenation and WGSR (water gas shift reaction) was also analyzed. The results showed that Fe(NO3)3·9H2O and iron naphthenate are catalytic active for anthracene hydrogenation with CO water gas shift, but Fe(NO3)3·9H2O is the better one. The conversion of CO water gas shift and anthracene hydrogenation increase with the increasing of CO initial pressure, reaction temperature and the concentration of Fe in Fe (NO3)3·9H2O. The conversion of anthracene hydrogenation is substantial when the concentration of Fe in Fe(NO3)3·9H2O is 0.08 wt% and CO initial pressure is 2 MPa. Anthracene hydrogenation consumed H2 generated from WGSR to promote WGSR, so there is a positive synergy between anthracene hydrogenation and WGSR.
    • FullText(HTML)
  • loading
    • References (18)
    • Related Articles

Catalog

    Turn off MathJax
    Article Contents

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return